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NCERT Solutions for Class 11 Chemistry Chapter 3 Classification of Elements and Periodicity in Properties

NCERT Solutions for Class 11 Chemistry Chapter 3 Classification of Elements and Periodicity in Properties covers the development of the periodic table, the modern periodic law, and periodic trends in atomic properties.

Overview of Topics & Subtopics (Click to Jump)

1. Development of the Periodic Table

Short Note:

• Mendeleev's Periodic Law: properties of elements are a periodic function of their atomic masses (had limitations, e.g., placement of isotopes).

• Modern Periodic Law: properties of elements are a periodic function of their atomic numbers, which resolved the anomalies of Mendeleev's table.

2. Nomenclature of Elements with Atomic Number > 100

Short Note:

• IUPAC has recommended a systematic nomenclature using numerical roots for elements with atomic number greater than 100, until their names are officially confirmed.

3. Periodic Trends in Properties

Short Note:

• Atomic Radius: decreases across a period (left to right) due to increasing nuclear charge, and increases down a group due to addition of new shells.

• Ionization Enthalpy: generally increases across a period and decreases down a group.

• Electron Gain Enthalpy: generally becomes more negative across a period, and less negative down a group.

• Electronegativity: generally increases across a period and decreases down a group.

4. Periodic Trends in Chemical Reactivity

Short Note:

• Metallic character decreases across a period and increases down a group, while non-metallic character shows the opposite trend.

NCERT Textbook Exercise Questions

What is the basic theme of organisation in the periodic table?
Answer: The basic theme is to classify elements in such a manner that similar elements are grouped together, based on the periodicity of their properties as a function of their atomic number (electronic configuration).
Arrange the following in order of increasing atomic radii: Na, Mg, Al, Si.
Answer: Since atomic radius decreases across a period from left to right, the increasing order is: Si < Al < Mg < Na.
Explain why the ionization enthalpy of nitrogen is higher than that of oxygen, though oxygen has a higher atomic number.
Answer: Nitrogen has a half-filled 2p³ configuration, which provides extra stability, making it harder to remove an electron. Oxygen has a 2p⁴ configuration where electron-electron repulsion in a paired orbital makes it slightly easier to remove an electron, so O has a lower ionization enthalpy than N despite being heavier.
Among the elements B, Al, C and Si, which has the highest first ionization enthalpy?
Answer: Carbon (C) has the highest first ionization enthalpy among these, since ionization enthalpy generally increases across a period and C is further right/up (smaller size, higher effective nuclear charge) compared to B, Al and Si.
Why are noble gases said to have zero electron gain enthalpy in the general trend discussion?
Answer: Noble gases have a completely filled stable electronic configuration, so they have no tendency to accept an additional electron, making their electron gain enthalpy close to zero (or slightly positive).
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Class 11 › Chemistry › Classification of Elements and Periodicity in Properties
Chapter notesRead the chapterPractice MCQsCheck what you rememberChapter test10 questions on one pageOnline testTest 1, 2 and 3, one question at a timePYQPrevious year questionsStudy materialPDF notes
Topics in this chapter: Historical Development & Modern Periodic LawIUPAC Nomenclature (Z > 100) & Electronic Configuration in BlocksPeriodic Trends in Physical PropertiesPeriodic Trends in Chemical Properties & Anomalous Behaviors